Producción Científica Profesorado

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)



Alvarez Hernandez, Alejandro

2004

Horacio Vásquez-Arciga, Aarón Pérez-Benítez, Alejandro Álvarez Hernández, Sylvain Bernesd and Miguel Ángel Méndez-Rojas. Bis(acetylsalicylato-k2O,O)diaquacadmium(II). Acta Crystallographica Section E Structure Reports. 2004, E60, m1621-m1623. ISSN 1600-5368. Reino Unido.


Abstract


In the title compound {systematic name: bis[2-(acetyloxy) benzoato-_2O,O0]diaquacadmium(II)}, [Cd(C9H7O4)2- (H2O)2], the CdII ion is located on a twofold rotation axis and is coordinated by two water molecules and two aspirinate ligands. The complex is almost isostructural with the corresponding zinc(II) complex. However, for the title compound, the aspirinate should be considered as an asymmetric chelating ligand, with CdÐO(carboxylate) bond lengths of 2.2777 (12) and 2.4121 (12) A Ê .



Producto de Investigación




Artículos relacionados

Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.

X-ray crystallographic study of neutral boron chelates with ?-diketones and tropolone

Facile synthesis of 1,3,6-oxadiazepines from 2,2?-(1,2-ethanediyldiimino)bisphenols

New boronates prepared from 2,4-pentanedione derived ligands of the NO2 and N2O2 type comparison to...

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

3-Benzoyl-2-isopropyl-4-alkyloxazolidin-5-ones as Efficient and Inexpensive Sources of Enantiopure ?...

Addition reaction of benzylbenzylidenenamine to lithium enolates of1,3-dioxolan-4-one: synthesis of ...

Enantioselective synthesis of ?-amino acids. Part 10: Preparation of novel ?,?- and ?,?-disubstitute...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

ChemInform Abstract: Facile Preparation of [4.4]Metacyclophane- and [5.5]Paracyclophane-Type Macrocy...