Producción Científica Profesorado

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicycles



Lopez Ruíz, Heraclio

2010

Heraclio López-Ruiz, Horacio Briseño-Ortega, Susana Rojas-Lima, Rosa Santilllán, Norberto Farfán. An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobycycles. Tetrahedron Letters 2010, Vol. 51, Núm. 19, pp 2633-2635 DOI: http://dx.doi.org/10.1016/j.tetlet.2010.03.027


Abstract


The 2-arylbenzoxazoles 3af were produced in moderate to excellent yields merely by stirring a potassium cyanide (3 equiv)-containing methanol solution of the borobicyclic compounds 1af at room temperature. These compounds were fully characterized spectroscopically [IR, 1H, and 13C NMR and X-ray analysis (3a)] and by elemental analysis.



Producto de Investigación




Artículos relacionados

Further insight into three center hydrogen bonding. Participation in tautomeric equilibria of hetero...

Enantioselective synthesis of ?-amino acids. Part 11: Diastereoselective alkylation of chiral deriva...

Furocoumarins of three species of the genus Dorstenia

Et3, and efficient Mediator for Xanthate Transfer Based Radical Processes.

Addition reaction of benzylbenzylidenenamine to lithium enolates of 1,3-dioxolan-4-one: synthesis of...

Enantioselective synthesis of ?-amino acids. Part 10: Preparation of novel ?,?- and ?,?-disubstitute...

Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles

r-Alkylation of (S)-Asparagine with Self-Regeneration of the Stereogenic Center: Enantioselective Sy...

Comparative Structural Characterization of the Biquaternized N-CH3 and N-BH3 Derivatives of the cis-...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...